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51.
The microstructure and electrochemical behavior of Mg–6Al–1Zn, Mg–6Al–1Zn–1Ga, Mg–6Al–1Zn–1Sn, and Mg–6Al–1Zn–0.5Sn–0.5Ga as anode materials in a 3.5 wt% NaCl solution are compared systematically. The results show that Sn alloying refines the second-phases of Mg–6Zn–1Al by promoting tiny granular Mg17Al12 phases containing Sn, and inspires their disperse distribution. However, the Ga results in the formation of semicontinuous reticular Ga containing Mg17Al12 phases. The comparison of discharge tests indicates that Mg–6Al–1Zn–1Sn has the highest discharge activity, and Mg–6Al–1Zn–1Ga displays the largest hydrogen evolution corrosion resistance in 3.5 wt% NaCl solution at 298 K. The synergy of Ga and Sn can shorten discharge activation time and promote low discharge potential. In addition, the utilization efficiencies of the alloys decrease as follows: Mg–6Al–1Zn–1Ga > Mg–6Al–1Zn–0.5Sn–0.5Ga > Mg–6Al–1Zn–1Sn > Mg–6Zn–1Al. This study illustrates that the Mg–6Al–1Zn–0.5Sn–0.5Ga alloy has acceptable utilization efficiency and desirable electrochemical activity, which implies that doping Ga and Sn obtains a balance between discharge activity and utilization efficiencies. 相似文献
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为了解决辛置煤矿东四延伸皮带巷掘进过程中由于大矸产生率过高造成巷道掘进效率低下的问题,在对大矸产生原因进行分析的基础上,提出采用锲直复合掏槽爆破方式代替原有的直眼掏槽爆破,并从巷道掘进效率、大矸产生率等方面进行详细对比分析。掘进采用锲直复合掏槽爆破方式后,大矸产生率从30%以上降低到20%以内,且最大矸石粒径从1000 mm×800 mm降低到500 mm×400 mm,巷道掘进进尺从1.5 m/d提升至3 m/d,应用效果显著。 相似文献
55.
铜硫分离中银的选择性导向回收 总被引:1,自引:0,他引:1
为了研究新型抑制剂在铜硫分离过程中对银浮选行为的影响, 采用石灰和LY作为硫抑制剂, 通过6种动力学模型, 分别考察了低碱和高碱环境下铜、银和铁的浮选回收率及动力学行为。结果表明, 6种动力学模型均可较好地拟合试验数据。石灰选择性较差, 在低碱性介质中对黄铁矿的抑制效果较弱, 在强碱性介质中不利于铜和银矿物的回收; 而LY在铜硫分离过程中表现出良好的选择性, 它可以在低碱和高碱环境下强烈抑制黄铁矿, 并在弱碱性矿浆中实现铜硫的高效分离, 同时诱导独立银矿物定向富集至铜精矿产品中。 相似文献
56.
《International Journal of Hydrogen Energy》2020,45(16):9803-9810
High ion selectivity and mechanical strength are critical properties for proton exchange membranes in vanadium redox flow batteries. In this work, a novel sulfonated poly(ether sulfone) hybrid membrane reinforced by core-shell structured nanocellulose (CNC-SPES) is prepared to obtain a robust and high-performance proton exchange membrane for vanadium redox flow batteries. Membrane morphology, proton conductivity, vanadium permeability and tensile strength are investigated. Single cell tests at a range of 40–140 mA cm−2 are carried out. The performance of the sulfonated poly(ether sulfone) membrane reinforced by pristine nanocellulose (NC-SPES) and Nafion® 212 membranes are also studied for comparison. The results show that, with the incorporation of silica-encapsulated nanocellulose, the membrane exhibits outstanding mechanical strength of 54.5 MPa and high energy efficiency above 82% at 100 mA cm−2, which is stable during 200 charge-discharge cycles. 相似文献
57.
在钳工锉配中,测量贯穿整个加工过程,千分尺和游标卡尺等传统测量方式往往不能满足加工要求。创新使用量块、百分表和正弦规进行测量,既提高了测量的效率和准确性,又保证工件的加工精度,缩短了加工工时,高质量地完成工件的加工。 相似文献
58.
冷却塔是火力发电厂循环水系统的重要设备,冷却塔的冷却效率对机组的微增功率有着比较重要的影响,冷却效率的提高有助于节约发电能耗。冷却塔的效率与其空气动力特性有着紧密的联系,本文以华电集团江苏分公司望亭发电有限公司3号机冷却塔的节能改造为例,研究了冷却塔内气流流场的特性,并阐述了针对该特性采取的技术措施在冷却塔优化改造中的应用实践。 相似文献
59.
Jialiang Pan Ziying Guo Zhenpeng Zhu Zishan Sun Tingting Zhang Jilin Zhang Xinguo Zhang 《Ceramics International》2018,44(17):20732-20738
High-efficient Ce3+/Tb3+ co-doped Ba3Y2B6O15 phosphors with multi color-emitting were firstly prepared, and their structural and luminescent properties were studied by XRD Rietveld refinement, emission/excitation spectra, fluorescence lifetimes as well as temperature-variable emission spectra. Upon 365?nm excitation, the characteristic blue Ce3+ band along with green Tb3+ peaks were simultaneously found in the emission spectra. Moreover, by increasing concentration of Tb3+, a blue-to-green tunable emitting color could be realized by effective Ce3+→Tb3+ energy transfer. Furthermore, all Ba3Y2B6O15: Ce3+, Tb3+ phosphors exhibit high internal quantum efficiency of ~?90%, while the temperature-variable emission spectra reveal that the phosphors possess impressive color stability as well as good thermal stability (T50 =?~?120?°C). The results indicate that these efficient color-tuning Ba3Y2B6O15: Ce3+, Tb3+ might be candidate as converted phosphor for UV-excited light-emitting diodes. 相似文献
60.
Serge Nyallang Nyamsi Mykhaylo Lototskyy Ivan Tolj 《International Journal of Hydrogen Energy》2018,43(50):22568-22583
Thermo-chemical energy storage based on metal hydrides has gained tremendous interest in solar heat storage applications such as concentrated solar power systems (CSP) and parabolic troughs. In such systems, two metal hydride beds are connected and operating in an alternative way as energy storage or hydrogen storage. However, the selection of metal hydrides is essential for a smooth operation of these CSP systems in terms of energy storage efficiency and density. In this study, thermal energy storage systems using metal hydrides are modeled and analyzed in detail using first law of thermodynamics. For these purpose, four conventional metal hydrides are selected namely LaNi5, Mg, Mg2Ni and Mg2FeH6. The comparison of performance is made in terms of volumetric energy storage and energy storage efficiency. The effects of operating conditions (temperature, hydrogen pressure and heat transfer fluid mass flow rates) and reactor design on the aforementioned performance metrics are studied and discussed in detail. The preliminary results showed that Mg-based hydrides store energy ranging from 1.3 to 2.4 GJ m?3 while the energy storage can be as low as 30% due to their slow intrinsic kinetics. On the other hand, coupling Mg-based hydrides with LaNi5 allow us to recover heat at a useful temperature above 330 K with low energy density ca.500 MJ m?3 provided suitable operating conditions are selected. The results of this study will be helpful to screen out all potentially viable hydrides materials for heat storage applications. 相似文献